The best way to learn Forth is to use Forth, and Brodie's "Starting Forth" is a good place to start with all of its examples. You can run those examples on Tali Forth 2.
I think the biggest issue I had when starting out was just learning enough words to do useful things. Tali Forth 2's documentation is pretty good once you know a little bit of Forth, so you should work your way through that after you get through Starting Forth. You can go to the Glossary in the Appendix (in manual.pdf found in the TaliForth2/docs folder) to see quick usage information for all of the words that Tali2 supports. Most of Tali2's words are from the ANS 2012 standard, and you can find even more detail on what a word does by referencing
https://forth-standard.org and I often use the magnifying glass at the top to search for words.
The good news is that you don't have to learn all the words at once, and once you start using Forth, you'll quickly learn the words most useful to you. My most used words are .S (see what is on the stack) and DUMP (see what is in memory) when I'm testing things out. The word that I always want to use and can never remember the name of is UNUSED (how many bytes of RAM left - and I just had to look it up again to write this), so don't feel bad if you can't remember a word you want to use and have to look it up.
If you get stuck, or just want to know how to approach something, feel free to let us know what you're trying to do and what you've tried so far, and we'll be happy to lend a hand. If you come up with a word you've created and want to know if that's the best way to do it, we can help with that too (although beware that different people might have different "best" answers
, but they will all be interesting and informative). You are also encouraged to share your "aha!" moments, of which there will be many if you really start digging deep into what Forth can do.