I made my comment without checking the datasheet -- I confess I got a little lazy.
But now that I do check it seems I was on the right track regarding mixed 5V and 3V operation, but not about groups of pins. IOW it appears there is only one "group," as cbscpe said.
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And just a reminder, cbmeeks -- as the OP it would be helpful for you to post or link to the datasheet, simply as a convenience for those who might read your post and wish to respond.
cheers,
Jeff
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