The simplist chip to add to a 6502 system to generate composite video (NTSC format) is the Motorola 6847. It is no longer available new, but is not difficult to get on ebay. The chip can generate a 32x16 text and block-graphic mode and 8 different lo-res graphics modes (4 in 2 colour, 4 in 4 colour.)
The simplist circuit for using this device requires an 8k RAM, a 74HC245, 2 74HC541 and 2 general purpose transistors (eg BC548 or 2N2222). This gives a monochrome output, which works well on a monochrome monitor but turns into a mess on a colour monitor because the pixel clock is at the same frequency as the colour subcarrier.
Once you have got it working, you can easily add colour encoding to give a colour output, however, the colour signal on a colour monitor is not as clear as the monochrome signal on a monochrome monitor.
See this thread
http://forum.6502.org/viewtopic.php?f=4&t=1909 for a previous discussion of this device. If you want to use this device, I suggest you search for the Acorn Atom schematic. The Acorn Atom used a 6502 & 6847 and the schematic shows exactly how to connect the two together.